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Abstract In recent decades, the interior regions of Eurasia and North America have experienced several unprecedentedly cold winters despite the global surface air temperature increases. One possible explanation of these increasing extreme cold winters comes from the so-called Warm Arctic Cold Continent (WACC) pattern, reflecting the effects of the amplified Arctic warming in driving the circulation change over surrounding continents. This study analyzed reanalysis data and model experiments forced by different levels of anthropogenic forcing. It is found that WACC exists on synoptic scales in observations, model’s historical and even future runs. In the future, the analysis suggests a continued presence of WACC but with a slightly weakened cold extreme due to the overall warming. Warm Arctic events under the warmer climate will be associated with not only a colder continent in East Asia but also a warmer continent, depending on the teleconnection process that is also complicated by the warmer Arctic. Such an increasingly association suggests a reduction in potential predictability of the midlatitude winter anomalies. 

Atomic layer deposition (ALD) is a technologically important method to grow thin films with high conformality and excellent thickness control from vapor phase precursors. The development of new thermal ALD processes can be limited by precursor reactivity and stability: reaction temperature and precursor design are among the few variables available to achieve higher reactivity, unlike in solution synthesis where the use of solvent and/or a catalyst can promote a desired reaction. To bridge this synthesis gap between vapor and solution, we demonstrate the use of an ultrathin coating layer of a vapor-phase compatible solvent—an ionic liquid (IL)— onto our growth substrate to perform ALD of SnO. Successful SnO deposition is achieved using tin acetylacetonate and water, a process that otherwise would require a stronger counter-reactant such as ozone. The layer of IL allows a solvent-mediated reaction mechanism to take place on the growth substrate. We report a growth per cycle of 0.67 Å/cycle at a deposition temperature of 100 °C in an IL comprised of 1-ethyl-3-methylimidazolium hydrogen sulfate. Characterization of the ALD films confirms the SnO film composition, and 1H and 13C NMR are used to probe the solvent-mediated ALD reaction, suggesting a solvent-mediated addition-elimination type mechanism forming acetone and acetate. Density functional theory calculations show that the ionic liquid solvent is beneficial to the proposed solvent-mediated mechanism by lowering the C-C bond cleavage energetics of acetylacetonate compared to the vapor phase. A general class of ligand-modification reactions for thermal ALD is thus introduced in this work. 

Abstract Droughts that exceed the magnitudes of historical variation ranges could occur increasingly frequently under future climate conditions. However, the time of the emergence of unprecedented drought conditions under climate change has rarely been examined. Here, using multimodel hydrological simulations, we investigate the changes in the frequency of hydrological drought (defined as abnormally low river discharge) under high and low greenhouse gas concentration scenarios and existing water resource management measures and estimate the time of the first emergence of unprecedented regional drought conditions centered on the low-flow season. The times are detected for several subcontinental-scale regions, and three regions, namely, Southwestern South America, Mediterranean Europe, and Northern Africa, exhibit particularly robust results under the high-emission scenario. These three regions are expected to confront unprecedented conditions within the next 30 years with a high likelihood regardless of the emission scenarios. In addition, the results obtained herein demonstrate the benefits of the lower-emission pathway in reducing the likelihood of emergence. The Paris Agreement goals are shown to be effective in reducing the likelihood to the unlikely level in most regions. However, appropriate and prior adaptation measures are considered indispensable when facing unprecedented drought conditions. The results of this study underscore the importance of improving drought preparedness within the considered time horizons. 

Painless and long-term sustained delivery of ocular drugs is enabled through the innovation of silicon nanoneedles. 

Abstract Historical wildfire events in California have shown a tendency to occur every five to seven years with a rapidly increasing tendency in recent decades. This oscillation is evident in multiple historical climate records, some more than a century long, and appears to be continuing. Analysis shows that this 5–7 year oscillation is linked to a sequence of anomalous large-scale climate patterns with an eastward propagation in both the ocean and atmosphere. While warmer temperature emerges from the northern central Pacific to the west coast of California, La Niña pattern develops simultaneously, implying that the lifecycle of the El Niño-Southern Oscillation that takes multiple years to form could be a trigger. The evolving patterns of the Pacific-to-North America atmospheric teleconnection suggest the role of tropical and subtropical forcing embedded in this lifecycle. These results highlight the semi-cyclical hydrological behavior as a climate driver for wildfire variability in California. 

Abstract Precipitation estimation based on passive microwave (MW) observations from low-Earth-orbiting satellites is one of the essential variables for understanding the global climate. However, almost all validation studies for such precipitation estimation have focused only on the surface precipitation rate. This study investigates the vertical precipitation profiles estimated by two passive MW-based retrieval algorithms, i.e., the emissivity principal components (EPC) algorithm and the Goddard profiling algorithm (GPROF). The passive MW-based condensed water content profiles estimated from the Global Precipitation Measurement Microwave Imager (GMI) are validated using the GMI + Dual-Frequency Precipitation Radar combined algorithm as the reference product. It is shown that the EPC generally underestimates the magnitude of the condensed water content profiles, described by the mean condensed water content, by about 20%–50% in the middle-to-high latitudes, while GPROF overestimates it by about 20%–50% in the middle-to-high latitudes and more than 50% in the tropics. Part of the EPC magnitude biases is associated with the representation of the precipitation type (i.e., convective and stratiform) in the retrieval algorithm. This suggests that a separate technique for precipitation type identification would aid in mitigating these biases. In contrast to the magnitude of the profile, the profile shapes are relatively well represented by these two passive MW-based retrievals. The joint analysis between the estimation performances of the vertical profiles and surface precipitation rate shows that the physically reasonable connections between the surface precipitation rate and the associated vertical profiles are achieved to some extent by the passive MW-based algorithms. 

Unprecedented heatwave-drought concurrences in the past two decades have been reported over inner East Asia. Tree-ring–based reconstructions of heatwaves and soil moisture for the past 260 years reveal an abrupt shift to hotter and drier climate over this region. Enhanced land-atmosphere coupling, associated with persistent soil moisture deficit, appears to intensify surface warming and anticyclonic circulation anomalies, fueling heatwaves that exacerbate soil drying. Our analysis demonstrates that the magnitude of the warm and dry anomalies compounding in the recent two decades is unprecedented over the quarter of a millennium, and this trend clearly exceeds the natural variability range. The “hockey stick”–like change warns that the warming and drying concurrence is potentially irreversible beyond a tipping point in the East Asian climate system.